Trace Organics

...DEDICATED TO PROTECTING AND ENHANCING THE PURITY, BEAUTY AND NATURAL FLOW OF THE NORTH FORK.

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The team: l-r Jeff Kelble, John Holmes, Bud Griswold

Trace Organics Monitoring

Project Underway


by John Holmes, Science Committee



The causes of the Shenandoah River fish kills in 2004,2005 and 2006 are not yet known. They are likely the result of several factors. Research to date has shown that the dying fish have suppressed immune systems and the research also shows that most of the male bass in the river are exhibiting intersex traits. Both may be exposure to and accumulation of certain organics in the fish tissues. Those organics can come from home use of drugs, shampoos and cleaners, as well as from specific agricultural or industrial activities. The nature and effects of these pollutants are beginning to receive national attention but they are not yet regulated, they are not removed by conventional sewage treatment methods, and we are still learning about the sources, the levels and the effects they are having.

In support of the Shenandoah River Fish Kill Task Force, the Friends of the North Fork of the Shenandoah River (FNFSR) recently deployed passive samplers in the North Fork that are designed to collect these trace organic compounds. When the samplers are removed from the river, they will be frozen and sent to a USGS lab in Missouri for detailed chemical analysis.

The organics of concern that may be altering the immune systems of the fish and causing the intersex traits in male bass are usually present in very low concentrations and are not easily measured. Information on the types and amounts of organics present in the river is needed so that researchers can determine if the soup of such organics present in the river is contributing to the intersex characteristics of the smallmouth bass.

Researchers at the USGS Columbia Environmental Research Center (CERC) in Missouri have developed membrane sampling devices that simulate fish uptake of these chemicals in the samples and thereby, in the river. Two types of passive samplers are being used: the Polar Organic Chemical Integrative Sampler (POCIS for polar organic chemicals and the Semi-Permeable Membrane Device (SPMD) for non polar organic chemicals. Each consists of a membrane enclosed fluid in a rigid container. As the water flows over the membrane, the samplers absorb the organics.

Samplers are being deployed in the river for a total of 12 weeks at two locations, near Woodstock and Mount Jackson, that were selected to match locations where fish and sediment samples are also being taken. Two samples, of six weeks duration each, will be taken at each of the two sites.

The USGS will analyze the samples. The results will be provided to other researchers (USGS, DEQ, DGIF, VCU, Virginia Tech) working with the Fish Kill Task Force so that they can relate the levels and types of trace organics in the river to the effects they are seeing. Also, FNFSR volunteer monitors are collecting water samples twice a month for testing by their sister organization the Friends of the Shenandoah River: they are also collecting samples during rain events at the request of the Department of Environmental Quality. This project has been funded in part by the Virginia Environmental Endowment.
Bud Griswold showing one of the monitors.
anchoring module in the river
assembling the monitoring device
close up of the device

Document Library

NameDescription
DocumentRiver Health ReportOrganic Chemicals in the North Fork
DocumentTrace Organic ReportOrganic Chemicals Passive Samplers - SPMD & POCIS
DocumentTrace Organic ReportInvestigation of Organic Chemicals Potentially Responsible for Martality and Intersex in Fish of the North fork of the Shenandoah River, VA, during Spring 2007
DocumentTrace Organic ReportEvidence of Endocrine Disruptors and Immune System Suppressors in the Results of the 2007 Trace Organics Monitoring Project on the North Fork of the Shenandoah River
DocumentAttachment 3Journal of Aquatic Health: Intersex (Testicular Oocytes) in Smallmouth Bass from the Potomac River and Selected Nearby Drainages
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Friends of the North Fork of the Shenandoah River
P. O. Box 746
Woodstock VA 22664
FNFSR office phone: 540-459-8550 email: friends@shentel.net
Leslie Mitchell-Watson
, executive director,
leslie.watson@fnfsr.org
Cindy Frenzel, education coordinator, cindy.frenzel@fnfsr.org